the anion [V0 (C(_2)O(_4))(_2)H(_2)0](^2 ) containing a distorted octahedral arrangement of oxygens about the metal atom. The two chelated oxalate groups have a cis arrangement with respect to one another and a water molecule occupies an apical position trans to the vanadyl group. A comparison of vanadium to oxygen bond lengths with corresponding vanadium to ligand distances in other octahedralvanadyl complexes
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